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Reactions of Aryl Grignard Reagents with 2,2,4-Trimethyl-3-hydroxy-3-pentenoic Acid β-Lactone 1

✍ Scribed by Berlin, K. Darrell; Cooper, M. H.

Book ID
121792555
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
294 KB
Volume
29
Category
Article
ISSN
0022-3263

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Reactions of phosphorous amides with 3-hydroxy-2,2,4-trimethyl-3-pentenoic acid β-lactone
✍ Wesley G. Bentrude; W.Delmar Johnson 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 230 KB

We wish to report results of a study of the reactions of [(CIi2)2N]9p1 c!H~oP[B(c&)~]~ and (QIso)2PW(GWe)2 with the lactone dimer (&) of dimethylketene. These results have bearing on the question of the relative nucleophllicitles or basicities of phosphorus and nitrogen towards car-(Received in USA