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Reactions of Aldehydes with Amines. II. A New Aldehyde Reagent 1

โœ Scribed by Singleton, F. G.; Pollard, C. B.


Book ID
127313180
Publisher
American Chemical Society
Year
1941
Tongue
English
Weight
289 KB
Volume
63
Category
Article
ISSN
0002-7863

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A new mild oxidation of amines to aldehy
โœ Huai Gu Chen; Paul Knochel ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 123 KB

## Summm: The silylamines 1, after conversion into their lithium or zinc salts, were readily oxidized by dry air under very mild conditions (-60' C to -20' C, 5-45 min.) into the corresponding aldehydes or ketones 2 in good yields. Our reaction conditions tolerate the presence of other oxidation s