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Reactions of agostic manganese complexes with molecular hydrogen

✍ Scribed by Seok Kyun Noh


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
365 KB
Volume
230
Category
Article
ISSN
0020-1693

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Kinetic studies of the hydrogen peroxide decomposition catalyzed by the dimeric Mn(I1)-gluconate complex, in alkaline medium, showed evidence for the oxidative cleavage of the ligand, leading to the formation of formaldehyde as one of Lie products. In the presence of a large excess of other hydroxyl