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Reactions of acylzirconocene chloride with nucleophiles: bimodal reactivity at β- and acyl carbons of α,β-unsaturated acylzirconocene chloride

✍ Scribed by Yuji Hanzawa; Kensuke Narita; Akito Kaku-uchi; Takeo Taguchi*

Book ID: 104210843
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 126 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01291-0

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✦ Synopsis

Reactions of a,b-unsaturated acylzirconocene chloride with nucleophiles showed novel bimodal reactivity at the band acyl carbons depending upon the nucleophile employed, and the formation of ketone a,b-dianionic species was also observed.

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