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Reactions of Acenaphthylene-1,2-quinone Monoxime with Some Phosphorus Ylides. - Synthesis of Acenaphtho [1,2-x]-Fused Compounds

โœ Scribed by Papageorgiou, Georgios ;Nicolaides, Demetrios ;Stephanidou-Stephanatou, Julia


Book ID
102365152
Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
267 KB
Volume
1989
Category
Article
ISSN
0947-3440

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โœฆ Synopsis


Very little is known about the reactions of phosphorus ylides with a-imino carbonyl compounds. Treatment of monoximes and monohydrazones of a-diketones with triphenylvinylphosphonium bromide gave moderate yields of 1 -hydroxypyrroles, 1 -aminopyrroles, or 2,3-dihydropyridazines '). The formation of five-and sixmembered rings appears to be dependent upon the geometry of the Scheme 1 / \ NOH Ph,P-CHCOOCH, &CHCOOCH3 / \ NOH 2 3(1,11)

12 as an oil (50 mg, 24%). -IR (liquid film


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