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Reactions of 4β,5-epoxy-5β-androstan-3-ones with hydrogen fluoride in pyridine

✍ Scribed by Bojan Hamlin Jennings; Joan Marie Bengtson


Book ID
118978459
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
926 KB
Volume
31
Category
Article
ISSN
0039-128X

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α,β -epoxyketone chemistry, II: reaction
✍ M. Neeman; J.S. O'Grodnick 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 223 KB

In Part I the reaction8 of HP with ateroldal a,p-epoxyketones were shown to occur reglospeoifically by two alternative modes, B or a\*, depending upon the eolvent employed.3 In neat CHC13, two model compound8 48,5aepoxy-178~hydroxy-endrosten-3-one lb end 4r,5a-epoxy-178-hydroxy-androeten-