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Reactions of 3,4,6-Trialkylphenols. II. Nitric Acid Reaction Products and their Decomposition

✍ Scribed by Albert, Harry E.; Sears, William C.

Book ID
126100816
Publisher
American Chemical Society
Year
1954
Tongue
English
Weight
675 KB
Volume
76
Category
Article
ISSN
0002-7863

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Preparation of adipic acid by oxidation
Preparation of adipic acid by oxidation of cyclohexanol and cyclohexanone with nitric acid: Part II. Reaction kinetics of the decomposition of 6-hydroxyimino-6-nitro hexanoic acid
✍ W. J. van Asselt; D. W. van Krevelen πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 328 KB

## Abstract The stablest intermediate product formed in the oxidation of cyclohexanol and cyclohexanone is 6‐hydroxyimino‐6‐nitro hexanoic acid (nitrolic acid). In the temperature range investigated it yields over 90% of adipic acid and N~2~O. In addition, a small amount of a still unidentified by‐