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Reactions of 3,3-dimethylbut-1-ene with deuterium oxide or deuterium over oxide catalysts

✍ Scribed by C Kemball; H.F Leach; B Skundric; K.C Taylor

Book ID: 113174374
Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 612 KB
Volume: 27
Category: Article
ISSN: 0021-9517
DOI: 10.1016/0021-9517(72)90178-9

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## Abstract Aromatic compounds bearing an __ortho__‐directing substituent may be deuterated by exchange with deuterium oxide in the presence of a range of cycloocta‐1,5‐dienyliridium(I)1,3‐dionate catalysts. The exchange takes place in several dipolar aprotic solvents and is directly applicable to