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Reactions of 3-hexyne with cobalt and iron carbonyls. Crystal structure and fluxionality of FeCo2(CO)9C2Et2

✍ Scribed by Aime, Silvio.; Milone, Luciano.; Osella, Domenico.


Book ID
126042882
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
648 KB
Volume
21
Category
Article
ISSN
0020-1669

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## The reaction of 2,3,5,6tetrakis(methylene)bicycle [2.2.2]octane (la) with Fez(CO), yields the two (q4-1,3diene)Fe(CO)3 isomers (2: exe; 3:endo) together with two bimetallic isomers (CIZH14)[Fe-(CO)3]2 (4:endo+xo; S:diexo). The reaction of la with RuB(CO)iZ yields the endo-(C1&14)Ru(CO)3 (6) and e