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Reactions of 3-Amino-substituted 5,6-Dihydro-2H-1,4-oxazines with α-Halo Ketones

✍ Scribed by N.A. Shtil'; A.M. Demchenko; A.P. Andrushko; A.N. Krasovsky


Book ID
110316487
Publisher
Springer US
Year
2001
Tongue
English
Weight
137 KB
Volume
37
Category
Article
ISSN
0009-3122

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1 ,ZOxazines, bis(trimethylsily1)amino-substituted / Hydrogenolysis / Deprotonation / Alkylation / Deuteration 1,2-Oxazine 1 was converted into an unusual condensation product 5 by treatment with tetra-n-butylammonium fluoride. The hydrogenolysis of 1 with Pd/C as catalyst provided the expected prim