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Reactions of 2H-3,4-dihydro-1,4-benzoxazin-6(8aH)-ones with 2,4,6-trimethylbenzonitrile oxide, III

✍ Scribed by M. Schubert-Zsilavecz; D. Gusterhuber; W. Likussar; G. Färber

Publisher
Springer Vienna
Year
1994
Tongue
English
Weight
443 KB
Volume
125
Category
Article
ISSN
0026-9247

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3-Benzyl-6-methyl-3,4-dihydro-2H-1,3-ben
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In the title molecule, C 16 H 17 NO, the dihedral angle between the phenyl and benzene rings is 28.4 (1) . The six-membered 3,4-dihydro-2H-1,3-oxazine ring adopts a screw boat conformation. In the crystal structure, weak C-HÁ Á Á(arene) interactions are present.

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O-Acetates of 4-hydroxy and 4-hydroxy-7-methoxy-2H-1,4-benzoxazln-3-ones reacted with nucleophlles such as phenols, lndoles and ethanethlol The maJor reaction center IS the positively-charged nitrogen atom