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Reactions of 2,3-diferrocenylcyclopropenone with methyllithium and phenyllithium

✍ Scribed by Elena I Klimova; Tatiana Klimova; Simón Hernández Ortega; Marı́ana Esquivelzeta Rabell; Lena Ruı́z Ramı́rez; Marcos Martı́nez Garcı́a


Book ID
108187839
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
299 KB
Volume
689
Category
Article
ISSN
0022-328X

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The reaction of 2-chlorobicyclo[2.2.1]he
✍ Paul G. Gassman; Thomas J. Atkins 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 172 KB

The reaction of methyllithium with 2-chlorobicyclo[2.2.1]heptene (j,) has been reported to produce P-methylbicyclo[2.2.l]heptene (x) in 73% yield.2 This appeared to be a unique example of a substitution of a vinylic chloride by an alkyl group through reaction with an organolithium reagent. Whereas,