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✦ LIBER ✦
Reactions of 2,3′-biindolyl: Synthesis of indolo[3,2-a]carbazoles
✍ Scribed by Tomasz Janosik; Jan Bergman
- Book ID
- 104209238
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 542 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0040-4020
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✦ Synopsis
2,Y-biindolyl (9) has been transformed into indolo[3,2-a]carbazoles 16a-b by means of formal [4 + 2] eycloadditions with co-formation of the Michael adducts 17a-b. The parent indolo[3,2-a]carbazole ( 6) has been prepared in one step from 9 in excellent yield. Several 3-substituted 2,3'-biindolyls have also been prepared in good yields and underwent further transformations, demonstrating the versatility of 2,3'-biindolyi (9) as a building block for synthesis of indolo[3,2-a]carbazoles.
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