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Reactions of 2-Methyl-6-aminomethylpyridine and 2-Thioamidopyridine with Group 2B Cations

✍ Scribed by Sutton, GJ

Book ID
115449199
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1963
Tongue
English
Weight
184 KB
Volume
16
Category
Article
ISSN
0004-9425

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## Abstract Optically active (1__S__)‐1‐methylbicyclo[2.2.1]heptan‐2‐one (25) was prepared by starting from (1__R__)‐bicyclo[2.2.1]heptan‐2‐one (21). Photolysis of the tosylhydrazone 8 of 25 generates, in part, 1‐methylbicyclo[2.2.1]heptane‐__endo__‐2‐diazonium ions (10) from which 1‐methylbicyclo[