Reactions of 2-(2′,4′-dinitrophenyl)-amino-2-deoxy-d-glucose, (DNP-d-glucosamine), and derivatives
✍ Scribed by P.F. Lloyd; M. Stacey
- Publisher
- Elsevier Science
- Year
- 1960
- Tongue
- French
- Weight
- 728 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
A 4-Hydroxy-L-proline glycoside of 2-amino-2-deoxy-D-glucose\* NOTES Previous papers from this laboratory described the synthesis and stability of W2,4\_dinitrophenylserine' and N-2,4-dinitrophenylthreonine' glycosides of 2-amino-2-deoxy-D-glucose. The present paper extends this series to 4-hydroxy-
1 ,3,4,6-Tetra-O-acetyl-2-alkoxycarbonylamino-2-deoxy-B-D-glucopyranoses and 3,4,6-tri-O-acetyl-2-alkoxycarbonylamino-2-deoxy-a-D-glnosyl bromides have been used as donors in glycosylation reactions with model alcohols. /3Glycosides were obtained in good yields and with a high degree of 1,2-tram ste
C-Glycosyl compounds represent a class of products used as chiral synthons' and as potential glycosidase inhibitors'. A number of methods have been devised for their synthesis3, but despite the biological importance of D-glucosamine, few C-glycosyl derivatives of this carbohydrate have been synthesi