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Reactions of 1,4- and 2,3-Diazadienes with Titanocene and Zirconocene Complexes of Bis(trimethylsilyl)acetylene: Acetylene Coupling or Substitution Including Subsequent C−H Activation, C−C Coupling, and N−N Cleavage to Heterobimetallic Complexes

✍ Scribed by Zippel, Thorsten; Arndt, Perdita; Ohff, Andreas; Spannenberg, Anke; Kempe, Rhett; Rosenthal, Uwe


Book ID
127211479
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
242 KB
Volume
17
Category
Article
ISSN
0276-7333

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The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,