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Reactions of 1,3-Diphenylisobenzofuran with Acetylenic Dienophiles

✍ Scribed by Berson, Jerome A.


Book ID
126209801
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
317 KB
Volume
75
Category
Article
ISSN
0002-7863

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Asymmetric Diels–Alder Reactions with Ch
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AbstractÐA new synthetic method is developed for the asymmetric Diels±Alder reactions of acetylenic dienophiles. Acetylenic Fischer carbene complexes with chiral pyrrolidines as the heteroatom stabilizing substituent were anticipated to block three of the four possible approaches of a diene and lead