𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Reactions of 1,1-bis(N,N-dimethylamino)-1,3-butadiene with olefins. Zwitterion formation and (4+2) cycloaddition as competing pathways.

✍ Scribed by Reiner Sustmann; Monika Rogge


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
256 KB
Volume
31
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Reactions of 1,1-bis(dimethylamino)-1,3-
✍ Sustman, Reiner ;Rogge, Monika ;NΓΌchter, Ursula ;Bandmann, Heinz πŸ“‚ Article πŸ“… 1992 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 884 KB

+ 2) Cycloaddition / Zwitterion formation / Ketene aminal l,l-Bis(dimethylamino)-1,3-butadiene (1) as a strong donor diene = 0.03 V vs. SCE, 1st IP, = 6.94 eV) is treated with acrylonitrile, dimethyl dicyanofumarate, and tetracyanoethylene. Cycloaddition with acrylonitrile is slow and requires eleva