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Reactions of 1-Naphthyl Radicals with Acetylene. Single-Pulse Shock Tube Experiments and Quantum Chemical Calculations. Differences and Similarities in the Reaction with Ethylene

โœ Scribed by Lifshitz, Assa; Tamburu, Carmen; Dubnikova, Faina


Book ID
127031409
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
941 KB
Volume
113
Category
Article
ISSN
1089-5639

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Formation of semiquinone radical in the
โœ Ravi Joshi; Tapan K. Ghanty; Tulsi Mukherjee ๐Ÿ“‚ Article ๐Ÿ“… 2009 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 638 KB

Embelin, 2,5-dihydroxy-3-undecyl-1,4-benzoquinone, has two intra-molecular hydrogen bonds between the quinone and hydroquinone groups present on the same ring. Therefore, it is expected to produce semiquinone radical in the oxidation as well reduction reactions. To investigate this aspect, kinetics