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Reactions of 1-hydro-and 1-halosilatranes with metal salts

✍ Scribed by N. F. Lazareva; V. A. Pestunovich

Book ID: 106520114
Publisher: Springer
Year: 2006
Tongue: English
Weight: 252 KB
Volume: 55
Category: Article
ISSN: 1573-9171
DOI: 10.1007/s11172-006-0326-8

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## Abstract Reaction of the 3,5‐diaryl‐1,2‐dithiolium salts 2 with the metal cyclopentadienides 4 and 9 leads to the formation of the tricyclic compounds 6 and 10 via a ring‐opened intermediate, which undergoes an intramolecular Diels‐Alder cyclization. Compounds 6 and 10 rearrange by treatment wit