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Reactions catalyzed by minerals. Part II. Chain termination in free-radical polymerizations

✍ Scribed by D. H. Solomon; Jean D. Swift

Publisher: John Wiley and Sons
Year: 1967
Tongue: English
Weight: 553 KB
Volume: 11
Category: Article
ISSN: 0021-8995
DOI: 10.1002/app.1967.070111216

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Reactions catalyzed by minerals. Part II

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## Abstract Properties of the radical polymerization of methyl methacrylate in the presence of cobalt(II) tetraphenylporphyrin ((TPP)Co^II^•) as a chain transfer catalyst are reported. Reversible addition of (L)Co‐H to macromonomers gives living character to the oligomer olefins that grow to higher