✦ LIBER ✦
Reactions between zinc(II) and tetra-azamacro-cycles of varying sizes. ΔH° and ΔS° contributions to the macrocylic effect
✍ Scribed by E. Gallori; E. Martini; M. Micheloni; P. Paoletti
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 165 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0020-1693
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✦ Synopsis
plexes are present in solution. We showed that ternary heterobinuclear complexes are present, of ;"e ;te] jCuCd(car)] 3+, [CuCd(car)Hr] '+, [CuCdcar It is 'noticeable that the deprotonated species are the most relevant both for binary and ternary systems, but they are dimeric for binary and monomeric for ternary systems. In the complex [CuCd-(car)H,]
- the second hydrogen ion displaced very probably comes from the pyrrole group of Hisresidue.