La presence de plusieurs centres reactionnels, la structure de grand cycle tres mobile, l'obtention difficile de criteres physiques differentiels , rendent delicat le contrble des reactions du cyclododecatriene -1,5 ,$I (Z , E , E) ou de ses derives (2). Ce travail est une contribution a l'explorati
✦ LIBER ✦
Reactions and applications oftrans-1,2-epoxy-(Z,E)-cyclododeca-5,9-diene
✍ Scribed by G. Lewandowski; E. Rytwińska
- Book ID
- 111490955
- Publisher
- Versita
- Year
- 2006
- Tongue
- English
- Weight
- 281 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0366-6352
No coin nor oath required. For personal study only.
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1-Alkenyldibromoboranes readily obtainable by the hydroboration of first alkyneswith dibromoborane-dimethyl sulfide followed by treatment with tribromoborane, react without any difficulty with second 1-alkynes as bromoborating agents to give (l-alkenyl)(Z-bromo-l-alkeny)bromoboranes (5). The reactio