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Reaction with alcohols of 1-bromo(chloro)-1,2-epoxyheptafluorobutanes and 1,2-epoxyperfluorobutane. Preparation of α-bromo-, α-chloro-, and α-alkoxyhexafluorobutyric acids esters

✍ Scribed by T. I. Filyakova; A. Ya. Zapevalov; M. I. Kodess; V. I. Saloutin


Book ID
111464164
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
438 KB
Volume
42
Category
Article
ISSN
1070-4280

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Kinetics of the reactions of cyclopropan
✍ P. J. Robinson; M. J. Waller 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 622 KB

## Abstract Thermolysis of the “all‐__cis__” compound 1α‐chloro‐2α,3α‐dimethylcyclopropane (A) at 550–607 K and 6–115 torr is a first‐order homogeneous non‐radical‐chain process giving penta‐1,3‐diene (PD) and HCl as products. The Arrhenius parameters are log~10~__A__(sec^−1^) = 13.92 ± 0.08 and __