A general consideration of the possible reaction routes of the hydrogen-electrode reaction leads to the classification of all the conceivable mechanisms into two groups according to the value of the stoichiometric number, Y, of the rate-determining step. The previous treatment on the validity, in t
Reaction Rates of the Hydrogen Isotopes
β Scribed by POLANYI, M.
- Book ID
- 109506038
- Publisher
- Nature Publishing Group
- Year
- 1934
- Tongue
- English
- Weight
- 227 KB
- Volume
- 133
- Category
- Article
- ISSN
- 0028-0836
- DOI
- 10.1038/133026b0
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A three-dimensional, quantum mechanical, coupled channel distorted wave approximation is used for calculating thermal rate constants for the isotopic D+ Hz, H + D2, Mu + Hz, and para to ortho H + Hz exchange reactions using the most accurate available potential surface. The calculated cross sections
The PODSs of the Hs system and its isotopic derivatives are used for computing exact adiabatic barriers we Fmd good agreement with experimentally measured ground and vibrationally excited activation energies. The theoretical results should stimulate further measurements of activation energies of vib