๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Reaction Rate Predictions Via Group Additivity. Part 3: Effect of Substituents with CH 2 as the Mediator

โœ Scribed by Sumathi, Raman; Carstensen, Hans-Heinrich; Green, William H.


Book ID
125960878
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
185 KB
Volume
106
Category
Article
ISSN
1089-5639

No coin nor oath required. For personal study only.


๐Ÿ“œ SIMILAR VOLUMES


Substituent effects on the disproportion
โœ Derek R. McDowell; Bert E. Holmes ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 412 KB ๐Ÿ‘ 2 views

Disproportionationkombination rate constant ratios, kd/&[, for the reactive collision between CF3CH2CHX + CF, radicals and between CF3CH2CHX + CF3CH2CHX radicals have been measured for X = CF, The kd/k, = 0.066 -t 0 01 3 when H is transferred to the CF3 radical and 0 I25 ? 0.025 for H transfer to th

Substituent effects on the disproportion
โœ John D. Ferguson; Bert E. Holmes ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 184 KB

## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 ยฑ 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 ยฑ 0.03 when the H is removed from the CH~3~ position in the reaction with t