Disproportionationkombination rate constant ratios, kd/&[, for the reactive collision between CF3CH2CHX + CF, radicals and between CF3CH2CHX + CF3CH2CHX radicals have been measured for X = CF, The kd/k, = 0.066 -t 0 01 3 when H is transferred to the CF3 radical and 0 I25 ? 0.025 for H transfer to th
โฆ LIBER โฆ
Reaction Rate Predictions Via Group Additivity. Part 3: Effect of Substituents with CH 2 as the Mediator
โ Scribed by Sumathi, Raman; Carstensen, Hans-Heinrich; Green, William H.
- Book ID
- 125960878
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 185 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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## Abstract Rate constant ratios, __k__~d~/__k__~c~ for the disproportionation/combination reaction have been measured as 0.07 ยฑ 0.02 when an H is removed from the CH~2~ position of the CF~3~CH~2~CHCH~3~ radical and as 0.24 ยฑ 0.03 when the H is removed from the CH~3~ position in the reaction with t
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