Model interactions have been studied by phosphorescence quenching to obtain a better understanding of the chain length dependence of interpolymeric chain end-chain end reactions such as those involved in the termination step of free radical polymerization. For small molecule-polymer interactions in
Reaction Rate of Small Diffusing Molecules on
β Scribed by Ronny Straube; Michael J. Ward; Martin Falcke
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 604 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0022-4715
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
An essentially new application of chronoamperometry is presented for the determination of homogeneous second-order rate constants for the reactions between small molecule reductants and redox proteins. The first part of the work is a comparison between stopped-flow kinetics and chronoamperometric ki
Small molecules in glassy polymers are considered to occupy sites with a distribution of free energies of dissolution. Then their diffusivity depends on concentration and temperature in the same way as it has been derived for hydrogen atoms in metallic glasses. For hydrogen it was shown that the tra