Reaction products from a discharge of N2 and H2S: The microwave spectrum of NH2SH
โ Scribed by F.J. Lovas; R.D. Suenram; W.J. Stevens
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 946 KB
- Volume
- 100
- Category
- Article
- ISSN
- 0022-2852
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An alternative mechanism of mercaptoborane, BH,SH, formation is proposed for the reaction of BzHs with SH2. It involves concerted elimination of BH3 and H2 from the H2SB2Hs complex and the highest energy on the pathway relative to SH, + B2H6 is 27.4 kcal/mol at MP4(SDTQ)/6-31 +G(2d, p)//MP2(FULL)/6\
Atomic resonance absorption spectroscopy (ARAS) was applied to measure S atoms, behind shock waves in COS/Hz pyrolysis or CSz/Hz photolysis systems. Both the pyrolysis of COS and the photolysis CSz was used to generate the S atoms, which subsequently reacts with H2 via the reaction: The photolysis