Reaction pathways for arylcarbamoyl radicals and the cyclization of o-substituted phenylcarbamoyl radicals
โ Scribed by Leardini, Rino; Tundo, Antonio; Zanardi, Giuseppe
- Book ID
- 125537833
- Publisher
- Royal Society of Chemistry
- Year
- 1981
- Weight
- 545 KB
- Category
- Article
- ISSN
- 1472-7781
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๐ SIMILAR VOLUMES
AbstractรFree radical cyclization reactions of alkylsulfonyl and alkylthio substituted aromatic amide derivatives are described. Carbon radicals can be generated efยฎciently from the sulfonyl radical induced reaction of allylsulfones or the oxidation of carbonyl compounds with manganese(III) acetate.
Pathways for the reaction of FCO+FCO on the ground state potential energy surface have been studied by using ab initio methods. Heats of reaction and barrier heights have been computed by using Moller-Plesset perturbation theory. The reaction of FCO t FCO has been found to form F2C202 molecule as an