Reductive cleavage of fully methylated, partially O-carboxymethylated cellulose had previously been shown to produce 4-O-acetyl-1,5-anhydro-2,3,6-tri-O-methyl-, -2-O-(methoxycarbonylmethyl)-3,6-di-O-methyl-, -3-O-(methoxycarbonylmethyl)-2,6-di-O-methyl-, -6-O-(methoxycarbonylmethyl)-2,3-di-O-methyl-
Reaction pathway in the base transformation of 2,4-O-benzylidene-1,6-di-O-p-tolylsulfonyl-d-glucitol into 1,3-anhydro-2,4-O-benzylidene-d-glucitol
โ Scribed by Henry B. Sinclair
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 345 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0008-6215
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๐ SIMILAR VOLUMES
## Nucleophilic addition-reactions of the title compound, prepared from the corresponding 3-nitrohex-2-enitol, were investigated under kinetically controlled conditions; such sterically bulky nucleophiles as tert-butyl peroxide and 2,4-pentanedionate ions (except in 1,Cdioxane) were found to enga
## Abstract Endโfunctionalized (1โ6)โ2,5โanhydroโ3,4โdiโ__O__โmethylโDโglucitols (3aโc) were synthesized by the anionic cyclopolymerization of 1,2:5,6โdianhydroโ3,4โdiโ__O__โmethylโDโmannitol (1), followed by treatment with a terminating agent such as 4โvinylbenzyl (2a), oxetanyl (2b), and methacry