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Reaction of α-oxides with naphthalene anion-radicals

✍ Scribed by A. A. Solov'yanov; L. I. Natanzon; K. S. Kazanskii

Book ID
112439933
Publisher
Springer
Year
1973
Tongue
English
Weight
183 KB
Volume
22
Category
Article
ISSN
1573-9171

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📜 SIMILAR VOLUMES

Configurational stability of cyclopropyl
Configurational stability of cyclopropyl radicals in electron-transfer reactions with naphthalene radical anion
✍ Gernot Boche; Dieter R. Schneider 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 203 KB

Cyclopropyl radicals normally undergo complete thermodynamic equilibration of configuration before they react, e.g., with bromine in the Hunsdiecker reaction'. Incomplete equilibration is normally due to steric or cage effectsa, and to surface effects when cyclopropyl halides are reduced with metals