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Reaction of α-halo organoindium reagents with carbonyl compounds and electron-deficient alkenes

✍ Scribed by Shuki Araki; Tsunehisa Hirashita; Ken Shimizu; Takahiro Ikeda; Yasuo Butsugan


Book ID
107857780
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
694 KB
Volume
52
Category
Article
ISSN
0040-4020

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Regioselective allylation and alkylation
✍ Shuki Araki; Tomoaki Horie; Motoshi Kato; Tsunehisa Hirashita; Hatsuo Yamamura; 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 186 KB

Triorganogallium and -indium reagents reacted with 0t,[]-unsaturated nitrile and carbonyl compounds to give 1.4-addition products regioselectively. The reaction of allylgallium 'and allylindium sesquihalides with ct,~unsatumted carbonyl compounds proceeded in a 1,2-addition mode, whereas a 1.4-addit