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Reaction of Unstabilized Iodonium Ylides with Organoboranes.

✍ Scribed by Masahito Ochiai; Yoshimi Tuchimoto; Nobuyuki Higashiura

Book ID
101962571
Publisher
John Wiley and Sons
Year
2004
Weight
190 KB
Volume
35
Category
Article
ISSN
0931-7597

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Metal-catalyzed carbenoid reactions with
Metal-catalyzed carbenoid reactions with iodonium and sulfonium ylides
✍ Paul MΓΌller; Daniel Fernandez; Patrice Nury; Jean-Claude Rossier πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 291 KB πŸ‘ 2 views

Transition metal-catalyzed decomposition of phenyliodonium and diphenylsulfonium ylides was investigated with regard to application in asymmetric carbenoid reactions. Phenyliodonium ylides react in the presence of Rh(II) catalysts with the same selectivity in inter-and intramolecular cyclopropanatio