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Reaction of tropylium salts with electrophilic reagents

✍ Scribed by M. E. Vol'pin; K. I. Zhdanova; D. N. Kursanov; V. N. Setkina; A. I. Shatenshtein

Book ID
112436218
Publisher
Springer
Year
1959
Tongue
English
Weight
128 KB
Volume
8
Category
Article
ISSN
1573-9171

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## Abstract The kinetics of the hydride transfer reactions of the dibenzo‐tropylium ion (2) with dimethylphenylsilane (5) and triphenylsilane (6) were used to determine its electrophilicity parameter __E__ = ‐0.71. The nucleophiles 7–9 react 10–40 times faster with 2 than expected from the linear f