Reaction of tropone with benzyne. Formation and photoisomerization of 6,7-benzobicyclo[3.2.2]nona-3,6,8-trien-2-one
β Scribed by Ciabattoni, Joseph.; Crowley, James E.; Kende, Andrew S.
- Book ID
- 126797487
- Publisher
- American Chemical Society
- Year
- 1967
- Tongue
- English
- Weight
- 277 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Recent comparisons between the photochemistry of cyclic unsaturated ketones and their exomethylene counterparts have revealed characteristic differences in reactivity between n-r\* and r -K \* excited states of conjugated systems. 1 In contrast to the typical photonarrangement of 2,5-cyclohexadienon
In a previous communication, we described the first example of l,&cycloaddition reaction of dehydrobenzene(1). In this communication we report another example of this type of reaction. In 1967, Ciabattoni, Crowley and Kende described the isolation of 6,7benzobicyclo[3.2.2]nona-3,6,8-trien-2-one (I