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Reaction of tris (trimethylsilyl) phosphate with salts of inorganic and organic acids

โœ Scribed by M. G. Voronkov; V. K. Roman; V. N. Senatorskaya

Book ID
112488538
Publisher
Springer
Year
1978
Tongue
English
Weight
183 KB
Volume
27
Category
Article
ISSN
1573-9171

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๐Ÿ“œ SIMILAR VOLUMES

The reaction of tris(trimethylsilyl)sila
The reaction of tris(trimethylsilyl)silane with acid chlorides
โœ M. Ballestri; C. Chatgilialoglu; N. Cardi; A. Sommazzi ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 268 KB

Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb