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Reaction of triphenylphosphine with organic hydrotrioxides

โœ Scribed by V. V. Shereshovets; F. A. Galieva; N. Ya. Shafikov; R. A. Sadykov; A. A. Panasenko; V. D. Komissarov


Book ID
112443210
Publisher
Springer
Year
1982
Tongue
English
Weight
160 KB
Volume
31
Category
Article
ISSN
1573-9171

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Reaction of polyperoxides with triphenyl
โœ Saraswathyammal Jayanthi; Kaushal Kishore ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 148 KB ๐Ÿ‘ 2 views

The triphenylphosphine deoxygenation of the polyperoxides, poly(styrene peroxide), poly(methyl methacrylate peroxide), and poly( a-methylstyrene peroxide) proceed via the phosphorane intermediates, which in the presence of moisture hydrolyze to give the respective diols. At higher temperatures and u