The triphenylphosphine deoxygenation of the polyperoxides, poly(styrene peroxide), poly(methyl methacrylate peroxide), and poly( a-methylstyrene peroxide) proceed via the phosphorane intermediates, which in the presence of moisture hydrolyze to give the respective diols. At higher temperatures and u
โฆ LIBER โฆ
Reaction of Triphenylphosphine Alkylenes with Activated Double Bonds
โ Scribed by Priv.-Doz. Dr. H. J. Bestmann; Dipl.-Chem. F. Seng
- Publisher
- John Wiley and Sons
- Year
- 1962
- Tongue
- English
- Weight
- 237 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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Transition-metal-catalyzed cross-coupling reactions of organometallic reagents with aryl iodides, bromides, and triflates as electrophiles are reliable tools for the regioselective syntheses of compounds with CA C H T U N G T R E N N U N G (sp 2 )-CA C H T U N G T R E N N U N G (sp 2 ) linkages. [1,