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Reaction of trimethyl- and triphenylstannate, (CH3)3Sn- and Ph3Sn-, with optically active 2-octyl bromide, chloride, and tosylate

✍ Scribed by San Filippo, Joseph; Silbermann, Joseph


Book ID
126129711
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
846 KB
Volume
104
Category
Article
ISSN
0002-7863

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Activation barriers of SN2 reactions: Fβˆ’
✍ Miroslav Urban; Ivan ČernuΕ‘Γ‘k; Vladimir Kellō πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 English βš– 378 KB

Activation barriers of the title reactions are calculated usmg a DZ + P basis set with diffuse p functions on negative ions. In the correlation effects, which are large and negatwe, the importance of single and triple excitations is stressed-The barrier for the reactmn of H-with CH3F is 12. kJ/molc.