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Reaction of trimethallylborane with bromopyridine—the first example of reversible 1,2-allylboration of pyridines

✍ Scribed by Yu. N. Bubnov; E. E. Demina; A. V. Ignatenko


Book ID
105595888
Publisher
Springer
Year
1997
Tongue
English
Weight
141 KB
Volume
46
Category
Article
ISSN
1573-9171

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Treatment of 2-alkyl pyridine N-oxides with acylating reagents represents an established procedure for the introduction of oxygen functionality into alkyl group at the ortho position of N heteroaromatic rings. We have reported the first example of asymmetric Boekelheide rearrangement applied to a se