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Reaction of trifluoromethylcarbene with cis- and trans-but-2-enes

โœ Scribed by Atherton, J. H.; Fields, R.


Book ID
120214582
Publisher
The Royal Society of Chemistry
Year
1967
Tongue
English
Weight
715 KB
Category
Article
ISSN
0022-4952

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Steric effects in the ene reaction.: The
โœ H.H. Wasserman; L.S. Keller ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 201 KB

In previous studies on the stereochemistry of benzyne addition to enol ethers and acetates we observed both stereoselective 2+2 cycloaddition and ene reaction. 1 In each series, however, we found that the proportion of ene product relative to cycloaddition was significantly larger with the trans-is