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Reaction of tributylphosphine (pentahaptocyclopentadienyl) copper (I) with iodoarenes

✍ Scribed by Martin Nilsson; Robert Wahren; Olof Wennerström

Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
218 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cyclopentadienylcopper

complexes with triphenyl-and triethylphosphine have been shown

recently to be of the pentahapto type. 1,2 The present investigation was undertaken to see whether a n-bonded copper complex would react with iodoarenes in a way similar to u-bonded copper compounds like alkyl-, 3 alkenyl-, 4 alkynyl-, ' phenyl-, ' and 2-thienyl copper. 7 If so, this would be in analogy with n-ally1 nickel complexes, which react with halogenoarenes to give unsymmetrical coupling products. 8

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