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Reaction of Titanate-Type Aldehyde Enolate with Ketones To Provide 3-Hydroxyaldehydes

✍ Scribed by Yachi, Kentaro; Shinokubo, Hiroshi; Oshima, Koichiro


Book ID
126072803
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
109 KB
Volume
121
Category
Article
ISSN
0002-7863

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Bidentate aluminum chelates derived from biphenol, binaphthol and catechol were found to be efficient catalysts for aldoltransfer reactions of ketone to ketone aldol adducts with aliphatic or aromatic aldehydes giving rise to the formation of aldol adducts of ketones to the aldehydes. In the presenc