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Reaction of thio and seleno phosphoric acid derivatives with O-thioacylated hydroxylamine

✍ Scribed by Grzegorz Cholewinski; Dariusz Witt; Radosław Majewski; Tadeusz Ossowski; Janusz Rachon

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
195 KB
Volume
18
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The reactivity of thio and seleno analogs of phosphoric acid 1b–f with O‐thioacylhydroxylamine 2 was examined. The experimental evidence for the proposed mechanism involving an N—O bond cleavage and a single electron transfer process (SET) from phosphate anions was collected. The influence of phosphoric acids 1 structure and their oxidation potentials on the course of the reaction and products 3, 4, 6, 7 distribution was presented. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:767–773, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20368

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