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Reaction of the Metal-Substituted Vinylidene Complex Cp'(CO)2Mn[:C:CHFp*] with Excess BuLi, Giving Acylated Dinuclear Bridging Alkenyl Complexes, Cp'MnCp*Fe[.mu.-CH:C(E)C(O)Bu](.mu.-CO)(CO)2 (E = H, Me): Confirmation of the Intramolecular 1,2-H Shift Mechanism Proposed for the Fluxional Process of the Cationic Diiron .mu.-Ethynyl Complexes [{(.eta.5-C5R5)Fe(CO)2}2(.mu.-C.tplbond.CH)]BF4

✍ Scribed by Akita, Munetaka; Takabuchi, Akio; Terada, Masako; Ishii, Naomi; Tanaka, Masako; Moro-oka, Yoshihiko


Book ID
121081786
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
509 KB
Volume
13
Category
Article
ISSN
0276-7333

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