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Reaction of the Heteronuclear Cluster [Cp*IrRu3(μ-H)2(CO)10] with Alkynes: Stereoselective Binding

✍ Scribed by Padmamalini Srinivasan; Weng Kee Leong


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
221 KB
Volume
2006
Category
Article
ISSN
1434-1948

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The Ditertiary-Phosphane-Bridged Heteron
✍ Yong Leng Kelvin Tan; Weng Kee Leong 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 271 KB

## Abstract A high‐yielding alternative synthesis of the dppm‐bridged heteronuclear cluster RuOs~3~(μ‐H)~2~(CO)~9~(μ‐CO)~2~(μ‐dppm) (1) [dppm = bis(diphenylphosphanyl)methane] has been developed. Thermolysis of 1 resulted in dephenylation of both phosphane groups to afford the butterfly cluster RuO