Reaction of tetracyclo[3.3.0.02,4.03,6]oct-7-ene with HCL and DCL; successive formation of edge- and corner-protonated cyclopropanes

✍ Scribed by I.D.C. Rood; G.W. Klumpp

• Publisher: Elsevier Science
• Year: 1983
• Tongue: French
• Weight: 268 KB
• Volume: 24
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)85966-3

✦ Synopsis

The title compound (I) is protonated at C(4). Product ratios depend on the solvent and are interpreted in terms of the opened, edge-protonated and corner-protonated forms, respectively, of the protonated cyclopropane ring of I. One of the comerprotonated forms is credited with laticyclic participation of the double bond.