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Reaction of tetracycline hydrochloride with N-chlorosuccinimide: X-ray crystal structure of the major product

✍ Scribed by Barton, Derek H. R.; Ley, Steven V.; Meguro, Kanji; Williams, David J.


Book ID
120572749
Publisher
The Royal Society of Chemistry
Year
1977
Tongue
English
Weight
143 KB
Volume
21
Category
Article
ISSN
0022-4936

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The X-ray crystal structures of the four stable phenylhydroxylamines (PhSOzNHOH, (PhS02)2NOH, PhS02NHOS02Ph, (PhS@)2NOSOZPh), and of PhS03'+H3NHNS02Ph are presented. The last of these is a by-product obtained during the isolation of PhS&NHOH (Piloty's Acid). The formation of and the bonding in these