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Reaction of tetrachloro-O-benzoquinone with 2-vinylfurans

✍ Scribed by N. Latif; N. Saddik; F. Mikhail

Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
88 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis

Duriw the cour.;e of' our utudie:.: on quinonoid comDunds, it has been found that tetrachloro-ebee:izoquino.r\e (I) has pronounced c.yzostatic activity. *This stimulated us to investigate its reactivity toward the known cytostatic agent, l,l-dicyano-2-(2-furyl) ethylene (IIa)'. It is found that (I) adds preferentially to the double bond of the fury1 residue to give the l,4-dioxen (IIla) leaving the 2-vinyl side chain intact. It adds similarly to the analogous 2-vinylfurans (iIb-e) in boiling benzene to give the corresponding 1,4-dioxcn derivatives, (IIIb-e). Thus, in this respect the isolated furan 11

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