Reaction of t-C4H9 · with HI: possible negative activation energies
✍ Scribed by Alan B. McEwen; David M. Golden
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 346 KB
- Volume
- 224
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The very low pressure reactor (VLPR) technique has been used to measure the bimolecular rate constant of the title reaction at 300 K. The rate constant is given by log k, (l/mol s) = (11.6 2 0.4) -(5.9 ? 0.6)/0 the equilibrium constant has also been measured at the same temperature and is given by K
i-C4HgON0 was photolyzed with 366-nm radiation at -8, 23, 55, 88, and 120°C in a static system in the presence of NO, O,, and N2. The quantum yield of i-C,H7CH0, @{i-C3H7CHO}, was measured as a function of reaction conditions. The primary photochemical act is and it proceeds with a quantum yield &